Abstract
This specification covers the standard practices for detecting susceptibility to intergranular attack in austenitic stainless steels. These practices include five intergranular corrosion tests, namely: (1) oxalic acid etch test for classification of etch structures of austenitic stainless steels; (2) ferric sulfate-sulfuric acid test, (3) nitric acid test and (4) copper-copper sulfate-sulfuric acid test for detecting susceptibility to intergranular attack in austenitic stainless steels; and (5) copper-copper sulfate-50% sulfuric acid test for detecting susceptibility to intergranular attack in molybdenum-bearing cast austenitic stainless steels. Methods for preparing the test specimens, rapid screening tests, apparatus setup and testing procedures, and calculations and report contents are described for each testing practice. The etch structure types used to classify the specimens are: step structure, dual structure, ditch structure, isolated ferrite, interdendritic ditches, end-grain pitting I, and end-grain pitting II.
Scope
1.1 These practices cover the following five tests:
1.1.1 Practice A—Oxalic Acid Etch Test for Classification of Etch Structures of Austenitic Stainless Steels (Sections 3 to 7, inclusive),
1.1.2 Practice B—Ferric Sulfate–Sulfuric Acid Test for Detecting Susceptibility to Intergranular Attack in Austenitic Stainless Steels (Sections 8 to 14, inclusive),
1.1.3 Practice C—Nitric Acid Test for Detecting Susceptibility to Intergranular Attack in Austenitic Stainless Steels (Sections 15 to 21, inclusive),
1.1.4 Practice E—Copper–Copper Sulfate–Sulfuric Acid Test for Detecting Susceptibility to Intergranular Attack in Austenitic Stainless Steels (Sections 22 to 31, inclusive), and
1.1.5 Practice F—Copper–Copper Sulfate–50 % Sulfuric Acid Test for Detecting Susceptibility to Intergranular Attack in Molybdenum-Bearing Cast Austenitic Stainless Steels (Sections 32 to 38, inclusive).
1.2 The following factors govern the application of these practices:
1.2.1 Susceptibility to intergranular attack associated with the precipitation of chromium carbides is readily detected in all six tests.
1.2.2 Sigma phase in wrought chromium-nickel-molybdenum steels, which may or may not be visible in the microstructure, can result in high corrosion rates only in nitric acid.
1.2.3 Sigma phase in titanium or columbium stabilized alloys and cast molybdenum-bearing stainless alloys, which may or may not be visible in the microstructure, can result in high corrosion rates in both the nitric acid and ferric sulfate–sulfuric acid solutions.
1.3 The oxalic acid etch test is a rapid method of identifying, by simple etching, those specimens of certain stainless steel grades that are essentially free of susceptibility to intergranular attack associated with chromium carbide precipitates. These specimens will have low corrosion rates in certain corrosion tests and therefore can be eliminated (screened) from testing as “acceptable.”
1.4 The ferric sulfate–sulfuric acid test, the copper–copper sulfate–50 % sulfuric acid test, and the nitric acid test are based on weight loss determinations and, thus, provide a quantitative measure of the relative performance of specimens evaluated. In contrast, the copper–copper sulfate–16 % sulfuric acid test is based on visual examination of bend specimens and, therefore, classifies the specimens only as acceptable or nonacceptable.
1.5 In most cases either the 15-h copper–copper sulfate–16 % sulfuric acid test or the 120-h ferric sulfate–sulfuric acid test, combined with the oxalic acid etch test, will provide the required information in the shortest time. All stainless grades listed in the accompanying table may be evaluated in these combinations of screening and corrosion tests, except those specimens of molybdenum-bearing grades (for example 316, 316L, 317, and 317L), which represent steel intended for use in nitric acid environments.
1.6 The 240-h nitric acid test must be applied to stabilized and molybdenum-bearing grades intended for service in nitric acid and to all stainless steel grades that might be subject to end grain corrosion in nitric acid service.
1.7 Only those stainless steel grades are listed in Table 1 for which data on the application of the oxalic acid etch test and on their performance in various quantitative evaluation tests are available.
1.8 Extensive test results on various types of stainless steels evaluated by these practices have been published in Ref (1).
1.9 The values stated in SI units are to be regarded as standard. The inch-pound equivalents are in parentheses and may be approximate.
1.10 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. (Specific precautionary statements are given in 5.6, 11.1.1, 11.1.9, and 35.1.)
