BS ISO 11916-1:2013

Soil quality. Determination of selected explosives and related compounds. Method using high-performance liquid chromatography (HPLC) with ultraviolet detection | Status: Current, Under review

1 Scope This part of ISO 11916 specifies the measurement of explosive and related nitrocompounds (as given in Table 1) in soils and soil materials. This part of ISO 11916 is intended for the trace analysis of explosives and related compounds by high-performance liquid chromatography (HPLC) using an ultraviolet (UV) detector. Under the conditions specified in this part of ISO 11916, concentrations as low as 0,1 mg/kg to 1 mg/kg dry matter can be determined, depending on the substance. Similar compounds, in particular various nitroaromatics, by-products and degradation products of explosive compounds may be analysed using this method. However, the applicability should be checked on a case-by-case basis. Table 1 — Explosive and related nitrocompounds for analysis Compound Abbreviation CAS-RN a Nitrobenzene NB 98-95-3 1,3-Dinitrobenzene 1,3-DNB 99-65-0 1,3,5-Trinitrobenzeneb 1,3,5-TNB 99-35-4 2-Nitrotoluene 2-NT 88-72-2 3-Nitrotoluene 3-NT 99-08-1 4-Nitrotoluene 4-NT 99-99-0 2,4-Dinitrotoluene 2,4-DNT 121-14-2 2,6-Dinitrotoluene 2,6-DNT 606-20-2 2,4,6-Trinitrotoluene 2,4,6-TNT 118-96-7 4-Amino-2,6-dinitrotoluene 4-A-2,6-DNT 19406-51-6 2-Amino-4,6-dinitrotoluene 2-A-4,6-DNT 35572-78-2 N-Methyl-N-2,4,6-tetranitroanilineb Tetryl 479-45-8 2,4,6-Trinitro-N-(2,4,6-trinitrophenyl)aniline Hexyl 131-73-7 1,3,5-Trinitrohexahydro-1,3,5-triazine RDX 121-82-4 1,3,5,7-Tetranitrooctahydro-1,3,5,7-tetrazocine HMX 2691-41-0 Pentaerythrityltetranitrateb PETN 78-11-5 a CAS-RN: Chemical Abstract Service-Registry Number b PETN, 1,3,5-TNB and tetryl gave poor interlaboratory trial results and their analysis could be problematic